Japanese Journal of Applied Physics · 2019 · 24 citations · 26 references
EngineeringMaterials EngineeringMaterials ScienceElectronic MaterialsSemiconductor DevicesSemiconductor MaterialsDislocations In SemiconductorsSemiconductor Crystal GrowthSemiconductor Device MaterialsSemiconductor SurfacesWide Band Gap SemiconductorsWide-bandgap SemiconductorsBreakdown VoltageDislocation DensityGallium NitrideGallium Nitride Power DevicesMetalorganic Chemical Vapor DepositionSeries ResistanceSurface Atomic StructureSurface Preparation Effects
Abstract This paper reports two inch gallium nitride (GaN) substrates fabricated from bulk GaN crystals grown in the near equilibrium ammonothermal method. 2″ GaN wafers sliced from bulk GaN crystals have a full width half maximum of the 002 X-ray rocking curve of 50 arcsec or less, a dislocation density of mid-10 5 cm −2 or less, and an electron density of about 2 × 10 19 cm −3 . The high electron density is attributed to an oxygen impurity in the crystal. Through extensive surface preparation, the Ga surface of the wafer shows an atomic step structure. Additionally, removal of subsurface damage was confirmed with grazing angle X-ray rocking curve measurements from the 114 diffraction. High-power p–n diode structures were grown with metalorganic chemical vapor deposition. The fabricated devices showed a breakdown voltage of over 1200 V with sufficiently low series resistance.
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Excellent crystallinity of truly bulk ammonothermal GaN
R. Doradziński, J. Garczyński, L. Sierzputowski et al. · Journal of Crystal Growth · 2008 · 320 citations