Disentangling structure-dependent antioxidant mechanisms in phenolic polymers by multiparametric EPR analysis

Lucia Panzella, Gerardino D’Errico, Giuseppe Vitiello, Marco Perfetti, Maria Laura Alfieri, Alessandra Napolitano, Marco d’Ischia

Chemical Communications · 2018 · 37 citations · 44 references

Concepts

Abstract

Excellent and selective correlations between the electron-transfer (ET) or hydrogen atom transfer (HAT) capacity (DPPH and lipid peroxidation inhibition assays) and EPR indices of π-electron spin delocalization delineate specific structural determinants of antioxidant activity in biomimetic phenolic polymers.

References

44