PLoS ONE · 2014 · 26 citations · 26 references
Natural SciencesChemistryAnalytical ChemistrySpectroscopic AnalysisSpectroscopyFluorescence SpectroscopyLaser SpectroscopyOptical SpectroscopySpectral Data ProcessingTime-resolved SpectroscopyFluorescence Spectroscopy AnalysisLaser-based DiagnosticsOil AnalysisSteady-state FluorescenceTime-resolved Fluorescence DetectionTime-resolved Fluorescence ImagingTime-resolved Fluorescence Spectroscopy
A time-resolved fluorescence (TRF) technique is presented for classifying motor oils. The system is constructed with a third harmonic Nd:YAG laser, a spectrometer, and an intensified charge coupled device (ICCD) camera. Steady-state and time-resolved fluorescence (TRF) measurements are reported for several motor oils. It is found that steady-state fluorescence is insufficient to distinguish the motor oil samples. Then contour diagrams of TRF intensities (CDTRFIs) are acquired to serve as unique fingerprints to identify motor oils by using the distinct TRF of motor oils. CDTRFIs are preferable to steady-state fluorescence spectra for classifying different motor oils, making CDTRFIs a particularly choice for the development of fluorescence-based methods for the discrimination and characterization of motor oils. The two-dimensional fluorescence contour diagrams contain more information, not only the changing shapes of the LIF spectra but also the relative intensity. The results indicate that motor oils can be differentiated based on the new proposed method, which provides reliable methods for analyzing and classifying motor oils.
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