Use of SiO2 nanoparticles as etch mask to generate Si nanorods by reactive ion etch

Eih-Zhe Liang, Chao-Jei Huang, Ching‐Fuh Lin

Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena · 2006 · 29 citations · 15 references

Concepts

Abstract

Silicon nanorods 20nm in diameter are fabricated by reactive ion etch (RIE) to study anisotropy and damage profile in decananometer scale. RIE of gas mixture of SF6∕O2 and SF6∕CHF3 is tuned to achieve high anisotropy. The gas specie of SF6∕O2 can reach 90% anisotropy, 84° taper angle, and 10:1 selectivity when SiO2 is used as the etching mask. The gas species of SF6∕CHF3 can reach 95% anisotropy, 87° taper angle, and 10:1 selectivity with Cr as the mask. The fabrication technique of nanorods uses a monolayer of silicon dioxide nanoparticle as the etching mask. The nanorods uniformly cover up the entire 2in. wafers with high density of 2×1011cm−2. Surface damageafter the etching process of nanostructures is monitored using the microwave-reflectance photoconductance decay with KOH removal-and-probe technique. Highly damaged silicon is found within a depth of 30nm and the lightly damaged part extends more than 100nm.

References

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