Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena · 1996 · 19 citations · 0 references
EngineeringMaterials EngineeringMaterials ScienceElectronic MaterialsMicrofabricationSemiconductor DevicesEtching ProcessesIii-v SemiconductorsMicrofabrication MaterialsSemiconductor Device MaterialsSemiconductor LasersWide-bandgap SemiconductorsActivation EnergyChemical EtchingEtch ChemistryEtch RateGallium Nitride (Gan) MaterialsLasersWet Chemical EtchingWet Etching
Several new wet and dry etch processes required for fabrication of microdisk lasers in the III nitrides have been developed. ICl/Ar electron cyclotron resonance plasmas produce etch rates of 1.3 μm/min for GaN and 1.15 μm/min for InN at 1000 W microwave power and 250 W of rf power. These rates are substantially faster than previously investigated Cl2/Ar or CH4/H2 plasma chemistries. Selectivities of 5–6 over AlN are obtained for these materials. Wet chemical etching of AlN and InXAl1−XN in KOH-based solutions was found to be a strong function of etch temperature and material quality. The activation energy for these materials was in the range 2–6 kcal/mol, typical of diffusion-controlled processes. The KOH solutions did not etch GaN or InN at temperature as high as 80 °C.