Oxidative Stability of Conventional and High‐Oleic Vegetable Oils with Added Antioxidants

Abstract

Abstract The oxidative stability of conventional and high‐oleic varieties of commercial vegetable oils, with and without added antioxidants, was evaluated using the oil stability index (OSI). Oil varieties studied were soybean (SOY), partially‐hydrogenated soybean (PHSOY), corn (CORN), sunflower (SUN), canola (CAN), high‐oleic canola (HOCAN), very high‐oleic canola (VHOCAN), oleic safflower (SAF) and high‐oleic sunflower (HOSUN). One or more commercial antioxidants were added to the four most stable oils at supplier‐recommended levels: rosemary extract (RM; 1,000 ppm), ascorbyl palmitate (AP; 1,000 ppm), tert ‐butylhydroquinone (TBHQ; 200 ppm), and mixed tocopherols (TOC; 200 ppm). OSI in hours (h) at 110 °C of the conventional oils were 5.2, 7.6, 8.4, 9.8, 10.9 and 14.3 h for SUN, SOY, CAN, CORN, PHSOY and SAF, respectively. OSI of high‐oleic variants were 12.9, 16.5 and 18.5 h for HOCAN, HOSUN and VHOCAN, respectively. Maximum OSI values for the four most stable oils when treated with antioxidants, were 40.9, 48.5, 48.8 and 55.7 h for HOCAN, VHOCAN, SAF and HOSUN, respectively. Addition of TBHQ, alone and in combination with other antioxidants, resulted in the greatest increase in oxidative stability of SAF and other high‐oleic oils evaluated. AP had a positive synergistic effect when used with TBHQ, while RM decreased TBHQ effectiveness.