Journal of The Electrochemical Society · 1983 · 81 citations · 0 references
Materials ScienceMaterials EngineeringPinhole GrowthMaterial AnalysisEngineeringEpitaxial GrowthCrystalline DefectsOxide ElectronicsSurface ScienceApplied PhysicsLeakage‐current IncreaseThin Film Process TechnologyReactive SputteringThin FilmsFilms DueAmorphous SolidHigh TemperatureThin Film Processing
Effects of high temperature annealing over the range 400°–1000°C on the leakage current of tantalum pentoxide films deposited by reactive sputtering are investigated. Leakage current of polycrystalline film (annealed above 700°C) is about 107–108 times larger than that of as‐deposited amorphous film. However, it is found that leakage current in film annealed at 600°C increases drastically as well, even though the films have not yet recrystallized. TEM observation reveals that pinholes ranging from 5 nm to 15 nm in diameter are formed near the bottom of the depressions in film annealed even at 600°C. Electrical properties of the films are discussed in terms of crystallographic properties such as pinhole growth and grain boundaries.