Volatiles from Delicious Apple Essence—Extraction Methods

Abstract

SUMMARY— The organic volatiles in commercial Delicious apple essence were extracted and reduced to an oil by five different extractants: isopentane, diethyl ether, charcoal (with elution by ether), liquid carbon dioxide, and 1,2‐dichloro‐1,1,2,2‐tetrafluoroethane. Identification and quantitative estimation of the maior constituents were made by gas‐liquid chromatography and mass spectrometry. Isopentane and the fluorocarbon were similar in action. Compared with ether they gave lower recoveries, especially for the low‐molecular‐weight alcohols, but they gave extracts with higher concentrations of esters and aldehydes and thus are useful for further composition studies. Liquid carbon dioxide gave an extract similar to that given by ether. Adsorption on charcoal gave generally good recoveries and was outstanding for alcohols. Panel tests indicated that the low‐molecular‐weight alcohols have only minor importance, if any, to apple aroma. A major proportion of the principal aroma‐bearing constituents was extracted by the methods used.