Surface and bulk defects in hydrogenated amorphous silicon and silicon-based alloy films

Tatsuo Shimizu, Xixiang Xu, Hideo Kidoh, Akiharu Morimoto, Minoru Kumeda

Journal of Applied Physics · 1988 · 52 citations · 8 references

Concepts

Abstract

The surface and bulk defects in a-Si:H, a-Si1−xCx:H, and a-Si1−xNx:H films were investigated by electron spin resonance (ESR) and constant photocurrent method. The thickness of the surface defective layer in a-Si:H films was determined for the first time by ESR. Applying various surface treatments, the free-surface layer proved to be much more defective than the interface layer. Both surface and bulk defect densities in a-Si1−xCx:H and a-Si1−xNx:H alloy films were also determined by ESR. The origin of the surface states is discussed, and the experimental results are explained by a simplified model of the distribution of surface defects.

References

8