Wireless Oxygen Sensors Enabled by Fe(II)-Polymer Wrapped Carbon Nanotubes

Abstract

Oxygen causes food spoilage and drug degradation, which is addressed commercially by modified atmosphere packaging. We report herein a wireless oxygen sensor, O₂-p-CARD, from solution processed Fe^II-poly(4-vinylpyridine)-single-walled carbon nanotube composites on commercial passive near-field communication tags. A large irreversible attenuation in the reflection signal of an O₂-p-CARD was observed in response to oxygen at relevant concentrations, enabling non-line-of-sight monitoring of modified atmosphere packaging. These devices allow for cumulative oxygen exposure inside a package to be read with a conventional smartphone. We have demonstrated that an O₂-p-CARD can detect air ingress into a nitrogen-filled vegetable package at ambient conditions. This technology provides an inexpensive, heavy-metal-free, and smartphone-readable method for in situ non-line-of-sight quality monitoring of oxygen-sensitive packaged products.