IEEE Transactions on Components Hybrids and Manufacturing Technology · 1993 · 31 citations · 14 references
Natural SciencesMaterials EngineeringMaterials ScienceInterface ScienceMetallic MaterialsMetallurgyAlloysMetal MaterialsMetallic BondingMetalsActivation EnergyContact ReliabilityCopper AlloysDegradationInterfacial MetallurgyKirkendall EffectMetallurgical BondingPore Formation Mechanisms
Works done on different Au-Sn-Cu and Au-Cu metallurgies in the inner lead bond (ILB) area is summarized. The influence of Kirkendall pore formation in the Cu-Au-Sn system as a degradation mechanism is shown. This effect, together with the formation of new types of ternary intermetallic compounds, is observed during thermal aging in contacts with a direct interface between the eutectic 80/20 Au-Sn alloy and Cu. The zeta-phase (Au/Sn 90/10) acts like a diffusion barrier, which inhibits the pore formation associated with Cu diffusion. The composition of the ternary intermetallic compounds, their growth constant, and activation energy is determined. The possibilities to increase the contact reliability by producing a reliable Au-Sn metallurgy during the ILB process are shown.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">></ETX>
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Max Hansen, K. Anderko, H. W. Salzberg · Journal of The Electrochemical Society · 1958 · 14.8K citations
On the porosity observed in the Kirkendall effect
F Seitz · Acta Metallurgica · 1953 · 186 citations
Diffusion-related behaviour of gold in thin film systems
M. R. Pinnel · Gold bulletin · 1979 · 64 citations