Japanese Journal of Applied Physics · 1990 · 56 citations · 8 references
EngineeringMaterials EngineeringMaterials ScienceElectronic MaterialsSemiconductor DevicesSemiconductor MaterialsDopingEpitaxial GrowthSemiconductor Crystal GrowthSemiconductor Device MaterialsSemiconductor InterfacesSemiconductor PhysicsEpitaxial Film GrowthEpitaxial Growth KineticsEpitaxial MaterialsMolecular Beam EpitaxySemiconductor DopingSilicon DopingSubstrate Orientation EffectsSubstrate Temperature Effects
The molecular beam epitaxial growth of Si-doped GaAs on slightly (1–5°) misoriented (111)A substrates was examined. Occupation sites of Si were greatly affected by the tilted angle, the flux ratio and the substrate temperature. In the growth on an exactly (111)A-oriented substrate at low flux ratio, substantially all Si atoms acted as acceptors. With increase of the tilted angle and/or the flux ratio and with decrease of the substrate temperature, the number of donor site Si atoms increased. A doping mechanism including preferential decomposition of As 4 molecules at the steps was proposed.
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