Molecular patterning through high-resolution polymethylmethacrylate masks

Qingling Hang, Yuliang Wang, Marya Lieberman, Gary H. Bernstein

Applied Physics Letters · 2002 · 41 citations · 11 references

Concepts

Abstract

Electron beam lithography was used to make nanometer trenches in thin polymethylmethacrylate (PMMA). After development, the wafers were dipped in an aqueous solution of the Creutz–Taube ion [(NH3)5Ru(pyrazine)Ru(NH3)5](o-toluenesulphonate)5 (CT5), and the PMMA was removed with acetone or dichloromethane. Atomic force microscopy and x-ray photoelectron spectroscopy were used to investigate the surface characteristics of wafers after dissolution of the PMMA and to confirm the binding of a monolayer of CT5 molecules on the wafer within the areas delimited by the PMMA trenches. This masking technique has so far been demonstrated to pattern 35 nm lines of a monolayer of CT5 molecules on silicon dioxide.

References

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