Electrochemical and Solid-State Letters · 2004 · 201 citations · 13 references
EngineeringMaterials EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryMicroelectromechanical SystemsBattery MaterialsElectrochemical CellsElectrochemical Energy StorageMems DesignMems FabricationMicroelectrode ArraysArray ElectrodesCarbon ElectrodesCarbon-based ElectrodesMicroelectrode FabricationMicroelectrode MaterialsPhotoresist EtchingThree-dimensional Electrode Arrays
We have demonstrated that carbon-microelectromechanical systems (C-MEMS), in which patterned photoresist is pyrolyzed in inert environment at high temperature, constitutes a powerful approach to building 3D carbon microelectrode arrays for 3D microbattery applications. High aspect ratio carbon posts (>10:1) are achieved by pyrolyzing SU-8 negative photoresist in a simple one step process. Lithium can be reversibly charged and discharged into these C-MEMS electrodes. Because of the additional volume of the posts, higher capacities are achieved with the 3D array electrodes as compared to unpatterned carbon films with the same projected electrode area. These novel electrode arrays represent one of the critical components for 3D batteries, which may be interconnected with C-MEMS leads to enable smart power management schemes.
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Lithium-ion rechargeable batteries
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Negative photoresists for optical lithography
Jane M. Shaw, Jeffrey D. Gelorme, N. LaBianca et al. · IBM Journal of Research and Development · 1997 · 339 citations
Ryan W. Hart, Henry S. White, Bruce Dunn et al. · Electrochemistry Communications · 2003 · 161 citations