Physical Review A · 2004 · 33 citations · 21 references
EngineeringChemistryInitial-state DistributionVisible Light SpectroscopyCharge TransportIon ProcessElectron PhysicElectron Transfer ProcessElectron SpectroscopyDirect ObservationMetal SurfaceIon EmissionCharge Carrier TransportPhysicsAtomic PhysicsPhysical ChemistryQuantum ChemistryNatural SciencesSurface ScienceApplied PhysicsCondensed Matter Physics
The electron transfer process in the interaction of a slow highly charged ion with a metal surface has been studied employing a microcapillary foil as a target. The combination of the target and a visible light spectroscopy allows us to directly evaluate the initial $(n,\ensuremath{\ell})$ distributions of the first transferred electrons. It was found that observed lines were primarily attributed to $\ensuremath{\Delta}n=1$ transitions with relatively high angular momenta $({\ensuremath{\ell}}_{i}\ensuremath{\gtrsim}4)$. A cascade analysis revealed that the electron is selectively transferred to $n\ensuremath{\approx}{q}_{in}+1$ states with a narrow distribution width of $\ensuremath{\delta}n\ensuremath{\approx}2$ (full width at half maximum). The average initial principal quantum number is consistent with the prediction of the classical over-barrier model.
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