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The influence of benzylic protection and allylic substituents on the CuCl-TMEDA catalyzed rearrangement of N-allyl-N-benzyl-2,2-dihaloamides to γ-lactams. Application to the stereoselective synthesis of pilolactam

Franco Ghelfi, Franco Bellesia, Luca Forti, Gianluca Ghirardini, Romano Grandi, Emanuela Libertini, Maria C Montemaggi, U. M. PAGNONI, Adriano Pinetti, L. DE BUYCK,

Tetrahedron · 1999 · 50 citations · 21 references

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21

A general method for the synthesis of amines by the rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions

Larry E. Overman · Journal of the American Chemical Society · 1976 · 291 citations

, , +5

Effects of temperature on atom transfer cyclization reactions of allylic .alpha.-iodo esters and amides

Dennis P. Curran, John Tamine · The Journal of Organic Chemistry · 1991 · 194 citations

, , +8

Synthesis of Primary Allylic Amines

Ridha Ben Cheikh, R. CHAABOUNI, André Laurent et al. · Synthesis · 1983 · 144 citations

, , +2

Transition metal-catalyzed radical cyclizations: a low-temperature process for the cyclization of N-protected N-allyltrichloroacetamides to trichlorinated .gamma.-lactams and application to the stereoselective preparation of .beta.,.gamma.-disubstituted .gamma.-lactams

Hideo Nagashima, Nobuyasu Ozaki, Masayuki Ishii et al. · The Journal of Organic Chemistry · 1993 · 135 citations

, , +8

Transition metal catalyzed radical cyclization: new preparative route to .gamma.-lactams from allylic alcohols via the [3.3]-sigmatropic rearrangement of allylic trichloroacetimidates and the subsequent ruthenium-catalyzed cyclization of N-allyltrichloroacetamides

Hideo Nagashima, Hidetoshi Wakamatsu, Nobuyasu Ozaki et al. · The Journal of Organic Chemistry · 1992 · 106 citations

, , +9