Stress- and strain-controlled measurements of interfacial shear viscosity and viscoelasticity at liquid/liquid and gas/liquid interfaces

Abstract

An interfacial rheometer for both stress- and strain-controlled measurements of shear rheological properties at liquid/liquid and gas/liquid interfaces is presented. The device is based on a rotating or oscillating biconical bob design in combination with a low friction electronically commutated motor system. The interfacial shear stress, viscosity, and dynamic moduli are obtained by solving the Stokes equations (low Reynolds number) along with the Boussinesq–Scriven interfacial stress tensor, which is used for the boundary conditions at the interface. An improved and simple numerical method for the calculation of the velocity distribution in the measuring cell is presented. The scope and limitations of the rheometer are discussed. Results from steady shear and oscillatory experiments as well as creep recovery and stress relaxation tests at both oil/water and air/water interfaces with adsorbed films of a globular protein (ovalbumin) and spread films of a surfactant (sorbitan tristearate) are presented.