Effects of epoxidation on the thermal oxidative stabilities of fatty acid esters derived from palm olein

Abstract

Abstract A variety of esters from the reactions of monoalcohols with palm olein were prepared, epoxidized by in situ peroxyacid techniques, and some of their physical properties were compared. The thermal oxidative stabilities of these esters and bis (2‐ethylhexyl) phthalate were studied. The esters were placed in an oven maintained at 120°C, and the loss of mass and acid, iodine, percent oxirane, hydroxyl, and peroxide values were monitored periodically. The epoxidized esters had higher densities and lower volatilities, and were more resistant toward oxidation than their unepoxidized counterparts. The stability of the oxirane was related to the initial acid value of the sample. Higher initial acid value resulted in a greater decrease in the oxirane content, indicating acid‐catalyzed cleavage of the oxirane ring.