Journal of Applied Physics · 2014 · 18 citations · 15 references
Natural SciencesElectrical EngineeringMaterials ScienceElectronic MaterialsNanomaterialsNanotechnologyDielectricsInterconnect TechnologySuperconducting MaterialsTransmission Electron MicroscopyBreakdown StrengthDielectric BreakdownElectrical BreakdownIn Situ Transmission Electron MicroscopyLow-k DielectricsNanoparticle FormationNanoparticlesTime-dependent Dielectric Breakdown
An in situ transmission-electron-microscopy methodology is developed to observe time-dependent dielectric breakdown (TDDB) in an advanced Cu/ultra-low-k interconnect stack. A test structure, namely a “tip-to-tip” structure, was designed to localize the TDDB degradation in small dielectrics regions. A constant voltage is applied at 25 °C to the “tip-to-tip” structure, while structural changes are observed at nanoscale. Cu nanoparticle formation, agglomeration, and migration processes are observed after dielectric breakdown. The Cu nanoparticles are positively charged, since they move in opposite direction to the electron flow. Measurements of ionic current, using the Triangular-Voltage-Stress method, suggest that Cu migration is not possible before dielectric breakdown, unless the Cu/ultra-low-k interconnect stacks are heated to 200 °C and above.
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Electron energy-loss spectroscopy in the TEM
R.F. Egerton · Reports on Progress in Physics · 2008 · 790 citations
Toughening of nanoporous glasses using porogen residuals
Daniel A. Maidenberg, Willi Volksen, Robert D. Miller et al. · Nature Materials · 2004 · 67 citations
Natural Sciences, Materials Engineering, Materials Science +11