Crystallization dynamics of nitrogen-doped Ge2Sb2Te5

R. M. Shelby, Simone Raoux

Journal of Applied Physics · 2009 · 111 citations · 23 references

Concepts

Abstract

The crystallization of amorphous Ge2Sb2Te5 (GST) doped with nitrogen is studied with pulsed laser heating. The crystallization time of sputter-deposited films is increased by doping by as much as 100× for nitrogen concentrations of the order of 12 at. % in as-deposited amorphous films. Suppression of the formation of critical crystal nuclei is found to be responsible. The crystallization of melt-quenched amorphous material is also slowed by doping but less dramatically.

References

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