Synthesis of cuprous oxide/silver (Cu ₂ O/Ag) hybrid as surface-enhanced Raman scattering probe for trace determination of methyl orange

Abstract

Recently, there have been publications on preparing hybrid materials between noble metal and semiconductor for applications in surface-enhanced Raman scattering (SERS) substrates to detect some toxic organic dyes. However, the use of cuprous oxide/silver (Cu 2 O/Ag) to measure the trace amounts of methyl orange (MO) has not been reported. Therefore, in this study, the trace level of MO in water solvent was determined using a SERS substrate based on Cu 2 O microcubes combined with silver nanoparticles (Ag NPs). Herein, a series of Cu 2 O/Ag x ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>x</mml:mi> <mml:mo>=</mml:mo> </mml:math> 1–5) hybrids with various Ag amounts was synthesized via a solvothermal method followed by a reduction process, and their SERS performance was studied in detail. X-ray diffraction (XRD) and scanning electron microscopy results confirmed that 10 nm Ag NPs were well dispersed on 200–500 nm Cu 2 O microcubes to form Cu 2 O/Ag heterojunctions. Using the as-prepared Cu 2 O and Cu 2 O/Ag x as MO probe, the Cu 2 O/Ag5 nanocomposite showed the highest SERS activity of all samples with the limit of detection as low to 1 nM and the enhancement factor as high as 4 × 10 8 . The logarithm of the SERS peak intensity at 1389 cm −1 increased linearly with the logarithm of the concentration of MO in the range from 1 nM to 0.1 mM.