Heme-Fe<sup>III</sup> Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: Fe<sup>III</sup>-O<sub>2</sub><sup>•–</sup> Complex H-Atom Abstraction Reactivity

Hyun Kim, Patrick J. Rogler, Savita K. Sharma, Andrew W. Schaefer, Edward I. Solomon, Kenneth D. Karlin

Journal of the American Chemical Society · 2020 · 59 citations · 95 references

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Abstract

-OOH species being formed via HAT reactivity of the partner ferric heme superoxide complex.

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95