Nanometer-Scale Distribution of a Lubricant Modifier on Iron Films: A Frequency-Modulation Atomic Force Microscopy Study Combined with a Friction Test

Abstract

chains of the oleyl esters fluctuating in the lubricant produced a repulsive force on the tip, which monotonically decayed with the tip-to-surface distance. The dynamic friction coefficient of sliding steel-lubricant-steel interfaces, which was separately determined using a friction tester, was compared with the force map determined on the iron film immersed in the corresponding lubricant. The complete monomolecular layer of the ester modifier on the static lubricant-iron boundary is a requirement for achieving smooth and stable friction at the sliding interface.