Concepedia

The Catalytic Pinacol Rearrangement of 1,2-Diols Using an Antimony(V) Salt

Tsunehiro Harada, Teruaki Mukaiyama

Chemistry Letters · 1992 · 26 citations · 5 references

DOI

Concepts

Abstract

Abstract In the presence of a catalytic amount of antimony(V) chloride or antimony(V) salt generated from antimony(V) chloride and silver hexafluoroantimonate, the pinacol rearrangement of several 1,2-diols or their trimethylsilyl ethers proceeds smoothly to give the corresponding ketones in good yields.

References

5

REDUCTIVE COUPLING OF CARBONYL COMPOUNDS TO PINACOLS AND OLEFINS BY USING TiCl4 AND Zn

Teruaki Mukaiyama, Toshio Sato, Jun‐ichi Hanna · Chemistry Letters · 1973 · 271 citations

, , +5

New reagents for the intermolecular and intramolecular pinacolic coupling of ketones and aldehydes

E. J. Corey, Rick Danheiser, Srinivasan Chandrasekaran · The Journal of Organic Chemistry · 1976 · 205 citations

, , +6

The Catalytic Friedel-Crafts Acylation Reaction Using a Catalyst Generated from GaCl3 and a Silver Salt

Teruaki Mukaiyama, Takashi Ohno, Takashi Nishimura et al. · Chemistry Letters · 1991 · 55 citations

, , +11

The Evaluation of Catalysts Generated from Lewis Acids and Silver Perchlorate in a Highly Stereoselective Glycosylation of 1-<i>O</i>-Acetyl-D-glucose

Teruaki Mukaiyama, Manabu Katsurada, Tohru Takashima · Chemistry Letters · 1991 · 47 citations

, , +16

The Catalytic Beckmann Rearrangement of Ketoxime Trimethylsilyl Ethers Using an Antimony(V) Salt

Teruaki Mukaiyama, Tsunehiro Harada · Chemistry Letters · 1991 · 24 citations

, , +6