Concepedia

REDUCTIVE COUPLING OF CARBONYL COMPOUNDS TO PINACOLS AND OLEFINS BY USING TiCl4 AND Zn

Teruaki Mukaiyama, Toshio Sato, Jun‐ichi Hanna

Chemistry Letters · 1973 · 271 citations · 4 references

DOI

Concepts

Abstract

Abstract Aldehydes and ketones were reduced by low valent titanium compound, produced from TiCl4 and Zn, to give the corresponding pinacols and olefins in high yields.

References

4

Lower valent tungsten halides. New class of reagents for deoxygenation of organic molecules

K. Barry Sharpless, Martha A. Umbreit, Marjorie T. Nieh et al. · Journal of the American Chemical Society · 1972 · 188 citations

, , +5

Mild procedure for transforming nitro groups into carbonyls. Application to the synthesis of cis-jasmone

John E. McMurry, Jack Melton · Journal of the American Chemical Society · 1971 · 98 citations

, , +7

One-step synthesis of 1,5-dienes involving reductive coupling of allyl alcohols

K. Barry Sharpless, Robert P. Hanzlik, Eugene E. Van Tamelen · Journal of the American Chemical Society · 1968 · 35 citations

, , +6

Titanium (III) Reduction of Sulfoxides

Tse‐Lok Ho, C. M. WONG · Synthetic Communications · 1973 · 32 citations

, , +8