Mechano‐ and Photochromism from Bulk to Nanoscale: Data Storage on Individual Self‐Assembled Ribbons

TLDR

A Pt(II) complex bearing an oligo‑ethyleneoxide pendant self‑assembles into ultralong ribbons that display mechanochromism when subjected to nanoscale mechanical stimuli via atomic force microscopy. AFM quantifies nanoscale mechanochromism arising from static pressure (piezochromism) and shear (tribochromism), and compares it to bulk pressure‑dependent luminescence measured with a diamond‑anvil cell. The ribbons can store high‑density information through AFM nanolithography, producing orange luminescence that contrasts cyan native emission, is selectively excitable by visible light, and can be concealed or erased by photochromic irradiation.

Abstract

A Pt(II) complex, bearing an oligo‐ethyleneoxide pendant, is able to self‐assemble in ultralong ribbons that display mechanochromism upon nanoscale mechanical stimuli, delivered through atomic force microscopy (AFM). Such observation paves the way to fine understanding and manipulation of the mechanochromic properties of such material at the nanoscale. AFM allows quantitative assessment of nanoscale mechanochromism as arising from static pressure (piezochromism) and from shear‐based mechanical stimuli (tribochromism), and to compare them with bulk pressure‐dependent luminescence observed with diamond‐anvil cell (DAC) technique. Confocal spectral imaging reveals that mechanochromism only takes place within short distance from the localized mechanical stimulation, which allows to design high‐density information writing with AFM nanolithography applied on individual self‐assembled ribbons. Each ribbon hence serves as an individual microsystem for data storage. The orange luminescence of written information displays high contrast compared to cyan native luminescence; moreover, it can be selectively excited with visible light. In addition, ribbons show photochromism, i.e., the emission spectrum changes upon exposure to light, in a similar way as upon mechanical stress. Photochromism is here conveniently used to conceal and eventually erase information previously written with nanolithography by irradiation.