Concepedia

Carbocycles via enantioselective inter- and intramolecular iridium-catalysed allylic alkylations

Stéphane Streiff, Carolin Welter, Mathias Schelwies, Gunter Lipowsky, Nicole Miller, Günter Helmchen

Chemical Communications · 2005 · 70 citations · 21 references

DOI

Concepts

Abstract

Carbocycles with > 90% ee were prepared via Ir-catalysed asymmetric allylic alkylation/ring closing metathesis sequences or enantioselective Ir-catalysed intramolecular allylic alkylations.

References

21

A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl<sub>2</sub>(CHR′)(PR<sub>3</sub>)<sub>2</sub>] and Its Reactions

Peter Schwab, Marcia B. France, Joseph W. Ziller et al. · Angewandte Chemie International Edition in English · 1995 · 1.5K citations

, , +16

Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I):  Catalytic, Kinetic Resolution of Allyl Carbonates

Christian Fischer, Christian Defieber, Takeyuki Suzuki et al. · Journal of the American Chemical Society · 2004 · 438 citations

, , +10

A Highly Effective Phosphoramidite Ligand for Asymmetric Allylic Substitution

Karine Tissot‐Croset, Damien Polet, Alexandre Alexakis · Angewandte Chemie International Edition · 2004 · 317 citations · Full text

, , +6

Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity

Christoph Kiener, Chutian Shu, Christopher D. Incarvito et al. · Journal of the American Chemical Society · 2003 · 292 citations

, , +16

Identification of an Activated Catalyst in the Iridium‐Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity.

Christoph Kiener, Chutian Shu, Christopher D. Incarvito et al. · ChemInform · 2004 · 227 citations · Full text

, , +14