Oxoiron(IV) porphyrin π-cation radical complexes with a chameleon behavior in cytochrome P450 model reactions

Two-State Reactivity as a New Concept in Organometallic Chemistry

Detlef Schröder, Sason Shaik, Helmut Schwarz · Accounts of Chemical Research · 2000 · 1.2K citations

Two-state Reactivity, Chemical Engineering, Engineering +10

High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450

John T. Groves, Robert C. Haushalter, Mikio Nakamura et al. · Journal of the American Chemical Society · 1981 · 709 citations

High-valent Iron-porphyrin Complexes, Chemical Analysis, Iron Metabolism +18

Investigation of the synthesis of ortho-substituted tetraphenylporphyrins

Jonathan S. Lindsey, Richard W. Wagner · The Journal of Organic Chemistry · 1989 · 697 citations

Derivative (Chemistry), Ortho-substituted Tetraphenylporphyrins, Donut Icon +7

Epoxidation reactions catalyzed by iron porphyrins. Oxygen transfer from iodosylbenzene

John T. Groves, Thomas E. Nemo · Journal of the American Chemical Society · 1983 · 463 citations

Oxygen Reduction Reaction, Chemical Engineering, Engineering +8

Uncoupling of the cytochrome P-450cam monooxygenase reaction by a single mutation, threonine-252 to alanine or valine: possible role of the hydroxy amino acid in oxygen activation.

Muneaki Imai, H. Shimada, Yoshihito Watanabe et al. · Proceedings of the National Academy of Sciences · 1989 · 370 citations · Full text

Aldo-keto Reductase, Molecular Biology, Redox Biology +17