Journal of The Electrochemical Society · 1995 · 45 citations · 0 references
EngineeringMaterials EngineeringMaterials ScienceElectronic MaterialsSemiconductor DevicesSemiconductor MaterialsCarrier TransportDopingIii-v SemiconductorsSemiconductor Device MaterialsWide-bandgap Semiconductor DevicesWide-bandgap SemiconductorsAnnealingCarrier ConcentrationDoping In Thin FilmsGallium NitrideHall EffectHole TransportP-type DopingPost-deposition Annealing
Very high quality p‐type thin films have been epitaxially grown on c‐sapphire substrates by the MOCVD technique in a multiwafer rotating‐disk reactor at 1040°C with a buffer layer of ∼200 Å grown at 530°C. The undoped films have a low n‐type background carrier concentration of with an x‐ray of 280 arc‐sec across the 1 in. substrate. Biscyclopentadienyl magnesium was used as the precursor , the p‐dopant. The Mg‐doped wafers retained an excellent surface morphology. In addition, after post annealing in ambient at ∼700°C for an hour, the Hall measurements show carrier concentration depending on flow rate, with a hole mobility of 10–20 cm2/V‐s which is the best mobility for those hole concentrations reported in the literature to date.