A novel total synthesis of the bioactive poly-substituted carbazole alkaloid carbazomadurin A

Palladium-catalyzed inter- and intramolecular cross-coupling reactions of B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with 1-halo-1-alkenes or haloarenes. Syntheses of functionalized alkenes, arenes, and cycloalkenes via a hydroboration-coupling sequence

Norio Miyaura, Tatsuo Ishiyama, Hirotomo Sasaki et al. · Journal of the American Chemical Society · 1989 · 547 citations

Natural Sciences, Chemistry, Catalysis +8

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

David E. Van Horn, Ei‐ichi Negishi · Journal of the American Chemical Society · 1978 · 284 citations

Natural Sciences, Chemistry, Catalysis +16

Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes

Ei‐ichi Negishi, David E. Van Horn, Tadao Yoshida · Journal of the American Chemical Society · 1985 · 246 citations

Natural Sciences, Chemistry, Catalysis +6

Synthesis of Biologically Active Carbazole Alkaloids Using Selective Transition-metal-catalyzed Coupling Reactions

Hans‐Joachim Knölker · Chemistry Letters · 2008 · 204 citations

Natural Sciences, Chemistry, Medicinal Chemistry +17

A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes

Cynthia L. Rand, David E. Van Horn, Mark W. Moore et al. · The Journal of Organic Chemistry · 1981 · 163 citations

Natural Sciences, Chemistry, Catalysis +7