David E. Van Horn

Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

Ei‐ichi Negishi, Nobuhisa Okukado, Anthony O. King et al. · Journal of the American Chemical Society · 1978 · 304 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +9

Nickel- or palladium-catalyzed cross coupling. 31. Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism

Ei‐ichi Negishi, Tamotsu Takahashi, Shigeru Baba et al. · Journal of the American Chemical Society · 1987 · 297 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +10

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

David E. Van Horn, Ei‐ichi Negishi · Journal of the American Chemical Society · 1978 · 284 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +10

Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes

Ei‐ichi Negishi, David E. Van Horn, Tadao Yoshida · Journal of the American Chemical Society · 1985 · 246 citations

Engineering, Alkene Metathesis, Altmetric Attention Score +10

Selective carbon-carbon bond formation via transition metal catalysis. 4. A novel approach to cross-coupling exemplified by the nickel-catalyzed reaction of alkenylzirconium derivatives with aryl halides

Ei‐ichi Negishi, David E. Van Horn · Journal of the American Chemical Society · 1977 · 163 citations

Materials Science, Chemical Engineering, Cross-coupling Reaction +12