Ei‐ichi Negishi

Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation

Ei‐ichi Negishi · Accounts of Chemical Research · 1982 · 1.1K citations

Engineering, Chemical Analysis, Altmetric Attention Score +16

Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides

Ei‐ichi Negishi, Anthony O. King, Nobuhisa Okukado · The Journal of Organic Chemistry · 1977 · 884 citations

Aryl Halides, Chemical Engineering, Cross-coupling Reaction +9

Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes

Ei‐ichi Negishi, Fredrik Cederbaum, Tamotsu Takahashi · Tetrahedron Letters · 1986 · 562 citations

Chemical Engineering, Heterocyclic, Grignard Reagents +5

Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides

Anthony O. King, Nobuhisa Okukado, Ei‐ichi Negishi · Journal of the Chemical Society Chemical Communications · 1977 · 559 citations

Inorganic Chemistry, Cross-coupling Reaction, Engineering +14

Recent Advances in Efficient and Selective Synthesis of Di-, Tri-, and Tetrasubstituted Alkenes via Pd-Catalyzed Alkenylation−Carbonyl Olefination Synergy

Ei‐ichi Negishi, Zhihong Huang, Guangwei Wang et al. · Accounts of Chemical Research · 2008 · 519 citations