PLoS ONE · 2013 · 18 citations · 53 references
Natural SciencesMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologySurface ScienceAtomic Force MicroscopyEtching ProcessesNanostructured SurfacesSilicon MaterialsSubstrate PreparationSurface OxidationAnodic OxidationEtchingOxide RemovalRelative Humidity EffectsSiliconSilicon EtchingSilicon OxidationWet Etching
In this letter, we investigate the fabrication of Silicon nanostructure patterned on lightly doped (10(15) cm(-3)) p-type silicon-on-insulator by atomic force microscope nanolithography technique. The local anodic oxidation followed by two wet etching steps, potassium hydroxide etching for silicon removal and hydrofluoric etching for oxide removal, are implemented to reach the structures. The impact of contributing parameters in oxidation such as tip materials, applying voltage on the tip, relative humidity and exposure time are studied. The effect of the etchant concentration (10% to 30% wt) of potassium hydroxide and its mixture with isopropyl alcohol (10%vol. IPA ) at different temperatures on silicon surface are expressed. For different KOH concentrations, the effect of etching with the IPA admixture and the effect of the immersing time in the etching process on the structure are investigated. The etching processes are accurately optimized by 30%wt. KOH +10%vol. IPA in appropriate time, temperature, and humidity.
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Theory of the oxidation of metals
N. Cabrera, N. F. Mott · Reports on Progress in Physics · 1949 · 2.9K citations
Soft lithography for micro- and nanoscale patterning
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Nanoimprint Lithography: Methods and Material Requirements
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