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A new simple synthesis of cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes from ketones and tetraphosphorus decasulfide
21
Citations
7
References
2000
Year
Inorganic ChemistryEngineeringHeterocyclicThiopivalophenone S-sulfidesNatural SciencesDiversity-oriented SynthesisOther IsomersOrganic ChemistryStereoselective SynthesisChemistryNew Simple SynthesisTetraphosphorus DecasulfidePharmacologyHeterocycle ChemistrySynthetic ChemistryEnantioselective Synthesis
The reaction of pivalophenones with tetraphosphorus decasulfide afforded cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes, which equilibrated to give other isomers in refluxing toluene via thiopivalophenones and thiopivalophenone S-sulfides.
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