The Stark Effect for a Rigid Asymmetric Rotor

Abstract

The Stark effect, arising from the interaction of a uniform electric field with a permanent electric dipole that is arbitrarily oriented within a rigid asymmetric rotor, and with a dipole induced in the rotor by the field, has been evaluated by perturbation methods. Tables are given for the perturbation of the energy levels so that, for J≤2, the rotational energies of an asymmetric molecule in an electric field may be readily approximated to terms quadratic in the electric field. The effect of accidental degeneracy upon the Stark effect and line intensities has been considered. A qualitative discussion of certain features of Stark patterns is given that may be useful in the identification of rotational spectral lines.