The Asymmetric Rotor I. Calculation and Symmetry Classification of Energy Levels
The Journal of Chemical Physics · 1943 · 457 citations · 10 references
Electric MachineEngineeringMechanical EngineeringRotor DynamicComputational ChemistryEnergy Level PatternsComputational MechanicsRigid Asymmetric RotorsVibronic InteractionBiophysicsEnergy LevelsPerturbation MethodPhysicsPhysical ChemistryQuantum ChemistryNatural SciencesMechanical SystemsAsymmetric RotorSymmetry Classification
A table of energy level patterns for rigid asymmetric rotors is given, by means of which this approximation to the rotational energies of all molecules up to J = 10 may be readily evaluated. The symmetry classification of each level is determined and expressed in terms of the K values of the limiting prolate- and oblate-symmetric rotors. A simple method is developed for calculating the transformation which diagonalizes the energy matrix and is applied to the derivation of perturbation formulas.
10
J. H. Van Vleck · Physical Review · 1929
948 citations
The Infrared Spectra of Polyatomic Molecules Part I
David M. Dennison · Reviews of Modern Physics · 1931
320 citations
On the Asymmetrical Top in Quantum Mechanics
S. C. Wang · Physical Review · 1929
255 citations
The Far Infrared Spectrum of Water Vapor
H. M. Randall, David M. Dennison, Nathan Ginsburg et al. · Physical Review · 1937
244 citations
Rotation of a Rigid Body in Quantum-mechanics
Nature · 1932
100 citations