The Asymmetric Rotor II. Calculation of Dipole Intensities and Line Classification
The Journal of Chemical Physics · 1944 · 263 citations · 4 references
Dipole IntensitiesEngineeringPhysicsAerospace EngineeringSymmetric RotorsMechatronicsAsymmetric Rotor IiLine ClassificationAerodynamicsRotor DynamicComputational ElectromagneticsRigid Asymmetric RotorsBiophysicsLine Strengths
A table of line strengths for rigid asymmetric rotors is given, by means of which to this approximation the relative intensities of all important rotational lines up to J < 13 for all bands of any molecule can be readily calculated, provided the asymmetry is roughly the same in the initial and final states. A classification of the irregularly spaced lines of the asymmetric rotor is made into ``sub-branches'' defined by the changes of the K values of the initial level in the limiting prolate and oblate symmetric rotors, and into ``wings'' which collect together lines of the sub-branches which have uniformly varying strength and Boltzmann factor, and fairly uniform spacing.
4
The Asymmetric Rotor I. Calculation and Symmetry Classification of Energy Levels
G.W. King, R. M. Hainer, Paul C. Cross · The Journal of Chemical Physics · 1943
457 citations
The Infrared Spectra of Polyatomic Molecules Part I
David M. Dennison · Reviews of Modern Physics · 1931
320 citations
The Analysis of the Hydrogen Sulfide Band at 10,100A
Paul C. Cross · Physical Review · 1935
57 citations
Concerning the <i>Q</i> Branch and Analysis of the Hydrogen Sulfide Band at 10100A
Paul C. Cross · The Journal of Chemical Physics · 1937
Transition Metal ChalcogenidesEngineeringChemical Analysis+13
12 citations