Australian Journal of Chemistry · 1976 · 184 citations · 0 references
PharmacyBiochemistryChemistryCarbohydrate BiochemistryCarbohydrate ChemistrySpectroscopyCarbohydrate CharacterizationCarbohydrate ConformationCarbohydrate SpectroscopyCarbohydrate StructureConformational AnalysisPolysaccharide StructureCarbohydrate Conformation In SolutionCarbohydrate Conformational AnalysisGlycosidic Bond ConformationNuclear Magnetic Resonance Spectroscopy Of SugarsOligosaccharide CharacterizationPolysaccharide Structural AnalysisPolysaccharide Structure ElucidationSolution Conformation Of Carbohydrates
All the resonances have been assigned in the 13C N.M.R. spectra of the hexuloses and some of their derivatives by the use of specifically deuterated compounds and comparison with related compounds. The composition of the hexuloses at equilibrium in aqueous solution has been determined and is discussed in terms of conformational analysis. The synthesis of D-fructose[l-D], D-fructose[3-D] and D-fructose[4-D] is described.