Concepedia

Chirality transmission via tandem sigmatropic rearrangement: Regio- and stereochemical outcome in the tandem Wittig—oxy-Cope sequence of allyl cis-5-methyl-2-cyclohexenyl ether

Noboru Sayo, Yasuhiro Kimura, Takeshi Nakai

Tetrahedron Letters · 1982 · 32 citations · 11 references

DOI

Concepts

References

11

Simple stereoselective version of the Claisen rearrangement leading to trans-trisubstituted olefinic bonds. Synthesis of squalene

William S. Johnson, Lucius Werthemann, William R. Bartlett et al. · Journal of the American Chemical Society · 1970 · 629 citations

, , +8

Nucleophilic and organometallic displacement reactions of allylic compounds: stereo-and regiochemistry

Ronald M. Magid · Tetrahedron · 1980 · 371 citations

, , +14

[3,3]Sigmatropic rearrangements of 1,5-diene alkoxides. Powerful accelerating effects of the alkoxide substituent

David A. Evans, A. M. Golob · Journal of the American Chemical Society · 1975 · 320 citations

, , +6

Allylic substitutions with retention of stereochemistry

Barry M. Trost, Thomas R. Verhoeven · The Journal of Organic Chemistry · 1976 · 126 citations

, , +7

[2,3]-Wittig rearrangement of unsymmetrical bis-allylic ethers. Facile method for regio- and stereoselective synthesis of 1,5-dien-3-ols

T. Nakai, K. MIKAMI, Shiro Taya et al. · Journal of the American Chemical Society · 1981 · 69 citations

, , +9