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A general approach to γ-lactones via osmium-catalyzed asymmetric dihydroxylation. Synthesis of (−)- and (+)-muricatacin.

Osmium-catalyzed Asymmetric DihydroxylationEngineeringBiochemistryNatural SciencesGeneral ApproachOrganic ChemistryChemistryNatural Product SynthesisAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering