Efficient stereodivergent synthesis of erythro- and threo-sphingosines: unprecedented reversal of the stereochemistry in the addition

.alpha.-Methoxy-.alpha.-trifluoromethylphenylacetic acid, a versatile reagent for the determination of enantiomeric composition of alcohols and amines

James A. Dale, David L. Dull, Harry S. Mosher · The Journal of Organic Chemistry · 1969 · 2.5K citations

Natural Sciences, Chemistry, Analytical Chemistry +6

Sphingosine inhibition of protein kinase C activity and of phorbol dibutyrate binding in vitro and in human platelets.

Yusuf A. Hannun, Carson R. Loomis, Alfred H. Merrill et al. · Journal of Biological Chemistry · 1986 · 1.2K citations · Full text

Life Sciences, Biochemistry, Pharmacology +15

The synthesis and configurational stability of differentially protected .beta.-hydroxy-.alpha.-amino aldehydes

Philip Garner, Jung Min Park · The Journal of Organic Chemistry · 1987 · 404 citations

Natural Sciences, Biochemistry, Chemistry +10

Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

Ei‐ichi Negishi, Nobuhisa Okukado, Anthony O. King et al. · Journal of the American Chemical Society · 1978 · 307 citations

Natural Sciences, Chemistry, Catalysis +16

Synthetic applications of organochlorozirconocene complexes

Peter Wipf, Heike Jahn · Tetrahedron · 1996 · 294 citations

Natural Sciences, Chemistry, Environmental Sciences +9