Concepedia

Cycloaromatization of a non-conjugated polyenyne system: Synthesis of 5H-benzo[d]fluoreno[3,2-b]pyrans via diradicals generated from 1-[2-{4-(2-alkoxymethylphenyl)butan-1,3-diynyl}]phenylpentan-2,4-diyn-1-ols and trapping evidence for the 1,2-didehydrobenzene diradical

Kazuhiro Miyawaki, Riho Suzuki, Tomikazu Kawano, I. Ueda

Tetrahedron Letters · 1997 · 142 citations · 19 references

DOI

Concepts

References

19

Chemistry and Biology of the Enediyne Anticancer Antibiotics

K. C. Nicolaou, Wei‐Min Dai · Angewandte Chemie International Edition in English · 1991 · 987 citations

, , +14

Reactive 1,4-dehydroaromatics

Robert G. Bergman · Accounts of Chemical Research · 1973 · 754 citations

, , +5

p-Benzyne. Generation as an intermediate in a thermal isomerization reaction and trapping evidence for the 1,4-benzenediyl structure

Richard R. Jones, Robert G. Bergman · Journal of the American Chemical Society · 1972 · 669 citations

, , +5

Thermal generation of .alpha.,3-dehydrotoluene from (Z)-1,2,4-heptatrien-6-yne

Elaine Y. Kuo, Nathaniel S. Finney · Journal of the American Chemical Society · 1989 · 274 citations

, , +5

Biradical formation from acyclic conjugated eneyne-allene system related to neocarzinostatin and esperamicin-calichemicin

Ryu Nagata, Hidenori Yamanaka, Eiichi Okazaki et al. · Tetrahedron Letters · 1989 · 227 citations

, , +6