Intramolecular radical cyclization of phenolic nitronates: Facile synthesis of annelated tropone and tropolone derivatives

Convergent total synthesis of (.+-.)-colchicine and (.+-.)-desacetamidoisocolchicine

David A. Evans, Steven P. Tanis, David J. Hart · Journal of the American Chemical Society · 1981 · 76 citations

Natural Sciences, Chemistry, Medicinal Chemistry +9

Synthesis of the spirocyclic center of fredericamycin a by phenoxy-enoxy radical coupling

Andrew S. Kende, Frank H. Ebetino, Toshiharu Ohta · Tetrahedron Letters · 1985 · 39 citations

Natural Sciences, Chemistry, Medicinal Chemistry +11

Mechanism of phenolic oxidative coupling reactions. Ferricyanide oxidation of 2,3',4-trihydroxybenzophenone, an example of a radical aromatic substitution mechanism

Patrick D. McDonald, Gordon A. Hamilton · Journal of the American Chemical Society · 1973 · 26 citations

Natural Sciences, Biochemistry, Chemistry +14

Radical reactions in aqueous solution: use of the <i>aci</i>-anion of nitromethane as a spin trap

Bruce C. Gilbert, R. O. C. Norman · Canadian Journal of Chemistry · 1982 · 23 citations

Natural Sciences, Chemistry, Chemical Kinetics +13

Intramolecular cyclisation of phenolic α-diazoketones. Novel synthesis of the spiro[4.5]decane carbon framework

Chuzo Iwata, Minoru Yamada, Y. SHINOO et al. · Journal of the Chemical Society Chemical Communications · 1977 · 23 citations

Natural Sciences, Chemistry, Organic Chemistry +6