Bioscience Biotechnology and Biochemistry · 1993 · 13 citations · 0 references
Natural SciencesChemistryLipid BiochemistryOrganic ChemistryFatty Acid ChemistryFatty Acid OxidationLipid ChemistryLipid OxidationPhotochemistryLight-induced Lipid OxidationLipid HydroperoxidesLipid Isomer AnalysisMass Spectral Data AnalysisMass Spectral IdentificationMass Spectral InterpretationOxidationPhotosensitized Reactions
The positional isomers of hydroperoxide prepared from methyl linoleate and methyl linolenate by photosensitized oxidation were analyzed by using the hydroperoxide-specific system of chemiluminescence-HPLC. Each isomer separated by HPLC was collected, reduced and identified by a mass spectral analysis as the trimethylsilyl derivative. Resolution of a racemate of the positional isomer established by chiral-phase HPLC.