Growth of Epitaxial CeO<sub>2</sub> Films on (1012) Sapphire by Halide Source Plasma Enhanced Chemical Vapor Deposition

Hiroshi Nakao, Hideki Yamawaki, Chikako Yoshida, H. Takauchi, Hirotaka Tamura, Naoki Yokoyama

Japanese Journal of Applied Physics · 1994 · 12 citations · 9 references

Concepts

Abstract

We grew epitaxial CeO 2 films on (1̄012) sapphire by halide source plasma enhanced chemical vapor deposition (halide-PECVD) using CeBr 3 and O 2 as source materials. We obtained amorphous films at substrate temperatures of 620° C, polycrystalline films at 680° C, and highly aligned films at 720°C. X-ray diffraction patterns show that (001) CeO 2 is parallel to (1̄012) sapphire, and electron channeling patterns show [110] CeO 2 aligned with [22̄01] sapphire. AFM shows very smooth films with a maximum variation of ± 2 nm. We grew YBCO film on CeO 2 /sapphire with a T c of 83 K.

References

9