Structures of mono-unsaturated triacylglycerols. V. The β′₁-2, β′-3 and β₂-3 polymorphs of 1,3-dilauroyl-2-oleoylglycerol (LaOLa) from synchrotron and laboratory powder diffraction data

Abstract

The crystal structures of the beta'(1)-2, the beta'-3 and the beta(2)-3 polymorphs of 1,3-dilauroyl-2-oleoylglycerol have been solved from powder diffraction data. The packing of the beta(2)-3 polymorph is similar to that of other cis mono-unsaturated triacylglycerols. Both the beta' polymorphs are crystallized in a novel type of packing in which one of the saturated lauroyl chains is packed side-by-side with part of the unsaturated oleoyl chain.