Model for the bleaching of WO3 electrochromic films by an electric field

Abstract

Measurements have been made of the current flow in amorphous WO3 films containing electrons and mobile cations. In a configuration in which electrons are extracted at one contact and cations at the other, the current decays as t−3/4 over many decades of time. By using space-charge current flow ideas, we develop a theory that gives the correct time dependence and magnitude of the current for this double-extraction phenomenon.