Die Makromolekulare Chemie · 1968 · 10 citations · 4 references
Macromolecular ChemistryEngineeringGlycobiologyDeuterium OxidePolysaccharideChemistryPolymersPolymer ChemistryBiochemistryBiocatalysisBiopolymersGradual PolymerisationBiomolecular EngineeringWater‐soluble MonomerMacromolecular ScienceNatural SciencesPolymer ScienceAbstract DeacetonationPolymer CharacterizationCarbohydrate-protein Interaction
Abstract Deacetonation of the crystalline monomer, 1.2:3.4‐di‐ O ‐isopropylidene‐6‐ O ‐methacryloyl‐α‐ D ‐galactopyranose(DGM, I) in 80% formic acid solution at 20°C gave the syrupy, water‐soluble monomer 6‐ O ‐methacryloyl‐α‐ D ‐galactopyranose (α‐GM) was a white crystalline compound which showed characteristic infrared absorption. The NMR spectrum of α‐GM in deuterium oxide was complicated by two variable: (i) mutarotation and (ii) gradual polymerisation. Syrupy GM was polymerised with ammonium persulphate to a water‐insoluble, cross‐linked hydrogel.
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Glyceryl methacrylate hydrogels
Miguel F. Refojo · Journal of Applied Polymer Science · 1965 · 85 citations
Biopolymer Gel, Hydrogels, Per Cent +13