Concepedia

Enthalpy-entropy Compensation

Enthalpy-Entropy Compensation is a thermodynamic phenomenon in which changes in enthalpy and entropy during a physical or chemical process exhibit a linear compensatory relationship, such that the resulting change in free energy is smaller than expected from the enthalpy change alone, commonly observed in biomolecular folding, alloy formation, and mixing processes.

379

Publications

21K

Citations

1.2K

Authors

479

Institutions

Publications per year

2017–2026

71

Parents

Publications

379

Enthalpy-entropy compensation. 2. Separation of the chemical from the statistical effect

Russell R. Krug, William G. Hunter, R. A. Grieger · The Journal of Physical Chemistry · 1976 · 804 citations

, , +11

Enthalpy-entropy compensation. 1. Some fundamental statistical problems associated with the analysis of van't Hoff and Arrhenius data

Russell R. Krug, William G. Hunter, R. A. Grieger · The Journal of Physical Chemistry · 1976 · 718 citations

, , +16

THE ENTHALPY-ENTROPY RELATIONSHIP AND ITS IMPLICATIONS FOR ORGANIC CHEMISTRY

John E. Leffler · The Journal of Organic Chemistry · 1955 · 710 citations

, , +9

A synthetic host-guest system achieves avidin-biotin affinity by overcoming enthalpy–entropy compensation

M.V. Rekharsky, Tadashi Mori, Cheng Yang et al. · Proceedings of the National Academy of Sciences · 2007 · 582 citations · Full text

, , +16

Entropy—enthalpy compensation: Fact or artifact?

Kim A. Sharp · Protein Science · 2001 · 420 citations · Full text

, , +17

1–5 of 379

Authors

1.2K

  1. FM
    Fleming Martínez

    Universidad Nacional de Colombia, Colombia

    9 publications · 507 citations

    9

    h-index

  2. JF
    Jack F. Douglas

    National Institute of Standards and Technology, United States

    7 publications · 262 citations

    7

    h-index

  3. AK
    Animesh Kumar Rakshit

    Maharaja Sayajirao University of Baroda, India

    6 publications · 321 citations

    6

    h-index

  4. TH
    Tadao Hakushi

    Himeji University, Japan

    6 publications · 652 citations

    6

    h-index

  5. YL
    Yu Liu

    Nankai University, China

    6 publications · 761 citations

    6

    h-index

1–5 of 1.2K

Institutions

479

  1. Universidad Nacional de Colombia

    Bogotá, Colombia

    9 h-index

    23 publications

    901 citations

  2. National Institute of Standards and Technology

    Gaithersburg, United States

    8 h-index

    15 publications

    408 citations

  3. Centre National de la Recherche Scientifique

    Paris, France

    8 h-index

    28 publications

    1.2K citations

  4. University of Cambridge

    Cambridge, United Kingdom

    8 h-index

    24 publications

    975 citations

  5. Kyoto University

    Kyoto, Japan

    5 h-index

    13 publications

    438 citations

  6. Chalmers University of Technology

    Gothenburg, Sweden

    5 h-index

    8 publications

    655 citations

  7. Delft University of Technology

    Delft, The Netherlands

    4 h-index

    9 publications

    269 citations

  8. Universidade Federal de Viçosa

    Viçosa, Brazil

    4 h-index

    11 publications

    351 citations

1–8 of 479

Venues

  1. The Journal of Physical Chemistry B

    23 publications · 998 citations

    17

    h-index

  2. Biochemistry

    16 publications · 996 citations

    15

    h-index

  3. Journal of the American Chemical Society

    JACS · 14 publications · 2K citations

    14

    h-index

  4. The Journal of Physical Chemistry

    10 publications · 2.1K citations

    10

    h-index

  5. The Journal of Chemical Physics

    10 publications · 398 citations

    10

    h-index

1–5