The development of an efficient photocatalyst with superior activity under visible light has been regarded as a significant strategy for pollutant degradation and environmental remediation. Herein, a series of WO₃/Ag₂CO₃ mixed photocatalysts with different proportions were prepared by a simple mixing method and characterized by XRD, SEM, TEM, XPS, and DRS techniques. The photocatalytic performance of the WO₃/Ag₂CO₃ mixed photocatalyst was investigated by the degradation of rhodamine B (RhB) under visible light irradiation (λ > 400 nm). The photocatalytic efficiency of the mixed WO₃/Ag₂CO₃ photocatalyst was rapidly increased with the proportion of Ag₂CO₃ up to 5%. The degradation percentage of RhB by WO₃/Ag₂CO₃-5% reached 99.7% within 8 min. The pseudo-first-order reaction rate constant of WO₃/Ag₂CO₃-5% (0.9591 min^-1) was 118- and 14-fold higher than those of WO₃ (0.0081 min^-1) and Ag₂CO₃ (0.0663 min^-1). The catalytic activities of the mixed photocatalysts are not only higher than those of the WO₃ and Ag₂CO₃ but also higher than that of the WO₃/Ag₂CO₃ composite prepared by the precipitation method. The activity enhancement may be because of the easier separation of photogenerated electron-hole pairs. The photocatalytic mechanism was investigated by free radical capture performance and fluorescence measurement. It was found that light-induced holes (h⁺) was the major active species and superoxide radicals (·O₂ ^-) also played a certain role in photocatalytic degradation of RhB.

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